Date:

Illinois engineers protect artifacts by graphene gilding

Gilding is the process of coating intricate artifacts with precious metals. Ancient Egyptians and Chinese coated their sculptures with thin metal films using gilding–and these golden sculptures have resisted corrosion, wear, and environmental degradation for thousands of years.

The middle and outer coffins of Tutankhamun, for instance, are gold leaf gilded, as are many other ancient treasures.

In a new study, Sameh Tawfick, an assistant professor of Mechanical Science and Engineering at the University of Illinois at Urbana-Champaign, inspired by this ancient process, has added a single layer of carbon atoms, known as graphene, on top of metal leaves–doubling the protective quality of gilding against wear and tear.

The study, “Gilding with Graphene: Rapid Chemical Vapor Deposition Synthesis of Graphene on Thin Metal Leaves,” is published in the journal Advanced Functional Materials. The researchers coated thin metal leaves of palladium with a single layer of graphene.

- Advertisement -

Metal leaves, or foils, offer many advantages as a scalable coating material, including their commercial availability in large rolls and their comparatively low price. By bonding a single layer of graphene to the leaves, Tawfick and his team demonstrated unexpected benefits, including enhanced mechanical resistance. Their work presents exciting opportunities for protective coating applications on large structures like buildings or ship hulls, metal surfaces of consumer electronics, and small precious artifacts or jewelry.

“Adding one more layer of graphene atoms onto the palladium made it twice as resistant to indents than the bare leaves alone,” said Tawfick. “It’s also very attractive from a cost perspective. The amount of graphene needed to cover the gilded structures of the Carbide & Carbon Building in Chicago, for example, would be the size of the head of a pin.”

Additionally, the team developed a new technology to grow high-quality graphene directly on the surface of 150 nanometer-thin palladium leaves–in just 30 seconds. Using a process called chemical vapor deposition, in which the metal leaf is processed in a 1,100°C furnace, the bare palladium leaf acts as a catalyst, allowing the gases to react quickly.

“Chemical vapor deposition of graphene requires a very high temperature, which could melt the leaves or cause them to bead up by a process called solid state dewetting,” said Kaihao Zhang, PhD candidate in MechSE and lead author of the study. “The process we developed deposits the graphene quickly enough to avoid high-temperature degradation, it’s scalable, and it produces graphene of very high quality.”

UNIVERSITY OF ILLINOIS COLLEGE OF ENGINEERING

Header Image –  An artist rendering of graphene gilding on Tutankhamun’s middle coffin (original photograph copyright: Griffith Institute, University of Oxford). R: Microscope image of a graphene crystal is shown on the palladium leaf. Although graphene is only a single atom thick, it can be observed in the scanning electron microscope. Here, a small crystal of graphene is shown to observe its edges. The team produces leaves where the graphene fully cover the metal surface.. Credit : Original photograph copyright: Griffith Institute, University of Oxford

- Advertisement -
Mark Milligan
Mark Milligan
Mark Milligan is an award winning journalist and the Managing Editor at HeritageDaily. His background is in archaeology and computer science, having written over 7,500 articles across several online publications. Mark is a member of the Association of British Science Writers (ABSW), the World Federation of Science Journalists, and in 2023 was the recipient of the British Citizen Award for Education and the BCA Medal of Honour.

Mobile Application

spot_img

Related Articles

Clusters of ancient qanats discovered in Diyala

An archaeological survey has identified three clusters of ancient qanats in the Diyala Province of Iraq.

16,800-year-old Palaeolithic dwelling found in La Garma cave

Archaeologists have discovered a 16,800-year-old Palaeolithic dwelling in the La Garma cave complex, located in the municipality of Ribamontán al Monte in Spain’s Cantabria province.

Burials found in Maya chultun

Archaeologists from the National Institute of Anthropology and History (INAH) have uncovered burials within a chultun storage chamber at the Maya city of Ek' Balam.

Archaeologists analyse medieval benefits system

Archaeologists from the University of Leicester have conducted a study in the main cemetery of the hospital of St. John the Evangelist, Cambridge, to provide new insights into the medieval benefits system.

Major archaeological discoveries in Mecklenburg-Western Pomerania

In an announcement by the State Office for Culture and Monument Preservation (LAKD), archaeologists excavating in the German state of Mecklenburg-Western Pomerania have uncovered seven Bronze Age swords, 6,000 silver coins, and two Christian reliquary containers.

Early humans hunted beavers 400,000-years-ago

Researchers suggests that early humans were hunting, skinning, and eating beavers around 400,000-years-ago.

Archaeologists find burial bundles with carved masks

A team of archaeologists from the PUCP Archaeology Program “Valley of Pachacámac” have uncovered over 70 intact burial bundles with carved masks.

Should the Elgin Marbles be returned?

The Elgin marbles are a collection of decorative marble sculptures taken from the temple of Athena (the Parthenon) on the Acropolis in Athens.